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Previously reported experiments revealed the presence of a small number of clusters or very small particles in the effluent of a nonthermal plasma reactor when treating a simulated engine exhaust mixture. These clusters are smaller than 7 nm. The quantity of clusters is orders of magnitude smaller than the particulate diesel or gasoline engine exhaust typically contains. In this report, we describe further experiments designed to determine the chemical composition of the clusters. Clusters were collected on the surface of a silicon substrate by exposing it to the effluent flow for extended time periods. The resulting deposits were analyzed by high mass resolution SIMS and by XPS. The SIMS analysis reveals NH4+, CH6N+, SO-, SO2-, SO3- and HSO4- ions. XPS reveals the presence of N and S at binding energies consistent with that of ammonium sulfate.

NOx reduction efficiency under simulated lean burn conditions is examined for a non-thermal plasma in combination with borosilicate glass, alumina, titania, Cu-ZSM-5 and Na-ZSM-5. The non-thermal plasma alone or with a packed bed of borosilicate glass beads converts NO to NO2 and partially oxidizes hydrocarbons. Alumina and Na-ZSM-5 reduce a maximum of 40% and 50% of NOx respectively; however, the energy cost is high for Na- ZSM-5. Cu-ZSM-5 converts less than 20% with a very high energy consumption. The anatase form of titania reduces up to 35% of NOx at a relatively high energy consumption (150J/L) when the catalyst is contained in the plasma region, but does not show any appreciable conversion when placed downstream from the reactor. This phenomenon is explained by photo-activation of anatase in the plasma.

Previous work done at the University of Michigan shows the capability of the vacuum-insulated catalytic converter (VICC) to retain heat during soak and the resulting benefits in reducing cold start emissions. This paper provides an improved version of the design which overcomes some of the shortcomings of the previous model and further improves the applicability and benefits of VICC. Also, newer materials have been evaluated and their effects on heat retention and emissions have studied using the 1-D after treatment model. Cold start emissions constitute around 60% to 80% of all the hydrocarbon and CO emissions in present day vehicles. The time taken to achieve the catalyst light-off temperature in a three-way catalytic converter significantly affects the emissions and fuel efficiency. The current work aims at developing a method to retain heat in catalytic converter, thus avoiding the need for light-off and reducing cold start emissions effectively.

As European and Chinese tailpipe emission regulations for gasoline light-duty vehicles impose particulate number limits, automotive manufacturers have begun equipping some vehicles with a gasoline particulate filter (GPF). Increased understanding of how soot morphology, reactivity, and GPF loading affect GPF filtration and regeneration characteristics is necessary for advancing GPF performance. This study investigates the impacts of morphology, reactivity, and filter soot loading on GPF filtration and regeneration. Soot morphology and reactivity are varied through changes in fuel injection parameters, known to affect soot formation conditions. Changes in morphology and reactivity are confirmed through analysis using a transmission electron microscope (TEM) and a thermogravimetric analyzer (TGA) respectively.

There is keen interest in understanding the origins of engine-out unburned hydrocarbons emitted during SI engine cold start. This is especially true for the first few firing cycles, which can contribute disproportionately to the total emissions measured over standard drive cycles such as the US Federal Test Procedure (FTP). This study reports on the development of a novel methodology for capturing and quantifying unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start. The method was demonstrated by applying it to a 4 cylinder 2 liter GTDI (Gasoline Turbocharged Direct Injection) engine for cold start conditions at an ambient temperature of 22°C. For this technique, the entirety of the engine exhaust gas was captured for a predetermined number of firing cycles.

A series of cold start experiments using a 2.0 liter gasoline turbocharged direct injection (GTDI) engine with custom controls and calibration were carried out using gasoline and iso-pentane fuels, to obtain the cold start emissions profiles for the first 5 firing cycles at an ambient temperature of 22°C. The exhaust gases, both emitted during the cold start firing and emitted during the cranking process right after the firing, were captured, and unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start were analyzed and quantified. The HCs emitted during gasoline-fueled cold starts was found to reduce significantly as the engine cycle increased, while CO and CO2 emissions were found to stay consistent for each cycle. Crankcase ventilation into the intake manifold through the positive-crankcase ventilation (PCV) valve system was found to have little effect on the emissions results.

Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOX emissions. Engine coolant is used to cool EGR coolers. The presence of a cold surface in the cooler causes fouling due to particulate soot deposition, condensation of hydrocarbon, water and acid. Fouling experience results in cooler effectiveness loss and pressure drop. In this study, possible soot deposition mechanisms are discussed and their orders of magnitude are compared. Also, probable removal mechanisms of soot particles are studied by calculating the forces acting on a single particle attached to the wall or deposited layer. Our analysis shows that thermophoresis in the dominant mechanism for soot deposition in EGR coolers and high surface temperature and high kinetic energy of soot particles at the gas-deposit interface can be the critical factor in particles removal.

Projected NOx and fuel costs are compared for a plasma-catalyst system and an active lean NOx catalyst system. Comparisons are based on modeling of FTP cycle performance. The model uses steady state laboratory device characteristics, combined with measured vehicle exhaust data to predict NOx conversion efficiency and fuel economy penalties. The plasma system uses a proprietary catalyst downstream of a plasma discharge. The active lean NOx catalyst uses a catalyst along with addition of hydrocarbons to the exhaust. For the plasma catalyst system, NOx conversion is available over a wide temperature range. Increased electrical power improves conversion but degrades vehicle fuel economy; 10 J/L energy deposition costs roughly 3% fuel economy. Improved efficiency is also available with larger catalyst size or increased exhaust hydrocarbon content. For the active lean NOx system, NOx conversion is available only in a narrow temperature range.